The quest for immortality is a common motivation for villains, most commonly occurring with old or aging villains, normally it is the fear of death that drives there pursuit. Although the pursuit of immortality itself is not exactly villainous, quite often it comes with a heavy price, such as sacrificing others for them to gain it.
This category also includes those who originally strived for immortality and succeeded, but came to regret it later on.
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- Darth Sidious (Vader)
- Dennis Watterghast
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- Diesel (Disney)
- Dimentio (Ben 10 show)
- Dio Brando (Super Vadimka)
- Disciples (TF2 FreakShow)
- Doma (Sunverse)
- Doom
- Doppelganger
- Dr. Devoniak (Citadel of the Heart)
- Dr. Eggman (Five Nights at Sonic's)
- Dr. Henry Miller
- Dr. Robotnik (SuperSonicJoseph)
- Dr. Schadenfreude (FreakShow)
- Dr.Jenna (Schlouden06)
- Dream (Dream SMP)
- Dusk
- DX-J9
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L
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P
R
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- Sargon
- Satan (Coolrash)
- Satan (Hazbin Hotel: Hellbound)
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- Scratch.EXE
- SeaSpy
- Simon Fitzgerald
- Sir Benedict Cumbersnatch
- Siren Head (Siren Head: The Movie)
- Slender Man (The Gray Chronicles)
- Solonos Evergrace
- Sonic The Hedgehog (Al-Shannona28 Villains)
- Sonic.EXE (Bratwurst)
- Starro the Conqueror (DC Cinematic Multiverse)
- Steven Maelstrom
- Strigo Wraist
- SynthetMedic
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W
- Waluigi (SMG4)
- Wario (SMG4)
- Warner Bros. Splatter
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- Well Dweller
- William Afton (AUCFNAFT)
- William Afton (Keksz1234)
- William Afton (Legacy of Fright)
- William Afton (Man on the Internet)
- William Afton (Mike's New Ghostly Family)
- William Afton (The Afton Story)
- William Afton (The Entire FNAF Lore In a Nutshell)
- Woody (Toy Story Remake)